ASAP J. Am. Chem. Soc., ASAP Article, 10.

Evidence for Dynamics on a 100 ns Time Scale from Single- and Double-Quantum Nitrogen-14 NMR in Solid Peptides

Simone Cavadini,† Anuji Abraham,*† Simone Ulzega,† and Geoffrey Bodenhausen†‡

Abstract:
The indirect detection of 14N spectra via protons in the manner of heteronuclear multiple-quantum correlation (HMQC) allows one to obtain single- (SQ) and double-quantum (DQ) 14N spectra in solids. A comparison of the SQ and DQ line widths as a function of temperature with simulations reveals motions in the tripeptide AAG with rates on the order of 107 s−1 at 49 °C.