MRC, Dybowski, 207Pb NMR

Magnetic Resonance in Chemistry
Vol: 44, Issue: 3, March 2006
pp. 357 - 365

Title: Solid-state 207Pb NMR studies of lead-group 16 and mixed transition-metal/lead-group 16 element-containing materials
Authors: Van Bramer, S. E.a; Glatfelter, A.b; Bai, S.b; Dybowski, C.b; Neue, G.c; Perry, D. L.d
Affiliations: a. Department of Chemistry, Widener University, Chester, PA 19013 USA
b. Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716 USA
c. Physical Chemistry, University of Dortmund, D‐44221 Dortmund, Germany
d. Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 USA
Keywords: 207Pb NMR; solid-state NMR; lead selenide; lead selenate; calcium plumbate; strontium plumbite; barium plumbite; lead borate; lead zirconate; lead tungstate; lead meta-tantalate; lead niobate; lead molybdate; lead meta-vanadate; lead sulfite; lead sulfate; materials
Abstract (English):

207Pb solid-state NMR studies have been conducted on binary lead-group 16 and mixed transition-metal/lead group 16 materials, correlating the NMR chemical shifts of the materials with their structures. The experimental results show that the 207Pb chemical shifts are strongly influenced by the local electronic structure. Data are reported for lead selenide, lead selenate, calcium plumbate, strontium plumbite, barium plumbite, lead borate, lead zirconate, lead tungstate, lead meta-tantalate, lead niobate, lead molybdate, lead meta-vanadate, lead sulfite, and lead sulfate. Copyright © 2006 John Wiley & Sons, Ltd.