Friday, March 31, 2006

Massiot, Chem Comm, 27Al-31P through bond correlations

Joel, please check

Chemical Communications, 2006, (Advance Article)

DOI: 10.1039/b600514d
Through-bond homonuclear correlation experiments in solid-state NMR applied to quadrupolar nuclei in Al–O–P–O–Al chains
Michaël Deschamps, Franck Fayon, Valérie Montouillout and Dominique Massiot
Through-bond homonuclear correlation experiments can be realised in solids between spins of type X, separated by four chemical bonds, in X–O–Y–O–X motifs, provided a J coupling between X and Y exists: central transitions of quadrupolar 27Al spins can be correlated via the J2 scalar coupling between 27Al (X) and 31P (Y) in materials featuring Al–O–P–O–Al motifs.

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